Add the users that you want the OneDrive for Business app to back up to the app.
Procedure
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From the navigation pane, go to Protect > Office 365.
The Office 365 apps page appears.
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Click the OneDrive for Business app.
The app page appears.
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On the Users tab, click Add, and then click Add Users.
The Add user dialog box appears.
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From the User group list, select a user group to add users to.
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From the Select users list, select the users to add.
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Click Add.